What it is and what causes itNitrate film is made by modifying long cellulose chains. Nitro side groups are grafted on to these cellulose chains (or polymers). Over time, as nitrate film is exposed to moisture, heat, and acids, the nitro side groups break away, producing nitrogen oxides in the film’s environment. When some nitrogen oxides react with moisture, nitric acid is produced. Nitrogen oxides and nitric acid readily promote silver corrosion, decompose gelatin emulsions, and catalyze the chemical reactions that cause further nitrate decay. Once begun, nitrate decay proceeds at an ever-increasing pace. The end result is the decomposition of the nitrate plastic itself.Gelatin softening and stickiness typically represents an intermediate phase of nitrate base decay. It is normally preceded by fading and discoloration of the image silver and followed by the decomposition of the nitrate plastic base. Nitrate decay is accompanied by an increasingly pungent, noxious odor long familiar to archivists. Decomposing gelatin may present as sticky bubbles on the surface of the film and cause negatives or wraps of film to adhere together (known as blocking). For film rolls, the blocking of convolutions of film eventually becomes irreversible, so that the film roll becomes a solid mass. This is colloquially referred to as the ‘hockey puck’ stage of nitrate decay. The last phase of nitrate decay involves the decomposition of the nitrate plastic into red/brown dust comprised of cellulose and colloidal silver. |
What you can doNitrate decay is hastened by the presence of moisture and heat, so storage of films in cold or frozen environments with a controlled, moderate relative humidity is essential. The control of temperature is the critical factor in stalling nitrate decay. Once nitrate decay begins, its progression is rapid. Nitrate film is considered a hazardous material, subject to strict guidelines for storage, handling and shipping. Nitrate film should be stored in accordance with ANSI/NFPA Standard 40 2011. |
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